Phosphorus Flame Retardants
Phosphorus FR additive benefits:
Can be both vapor phase and condensed phase flame retardants.
Can be very effective at lowering heat release rate at low loadings of additive.
Phosphorus FR additive drawbacks:
Tend to generate more smoke and carbon monoxide during burning.
Not effective in all polymers.
Starting to be under regulatory scrutiny.
Newer technology (1950s). A mature technology but lots of other possible chemical structures to explore and use for flame retardancy.